Analysis of the kinetics of the flow of wetting films in flotation processes

The work is aimed at obtaining new knowledge in the field of hydrodynamic interaction of hydrophobic surfaces in order to increase the extraction of mineral microdispersions by the flotation method. In this work, to increase the recovery of finely dispersed gold, the effect of a high rate of sticking of small particles to large ones was used by introducing carrier minerals into the pulp in the form of a crude concentrate isolated from a part of the ore. In this mode of separation of minerals in the flotation system, the content of the target component simultaneously increases, which contributes to the growth of its extraction into a commercial product. Moreover, in the operation that produces a commercial product, the flotation system is aerated for a short time (approximately 15–25% of the total) with air bubbles filled with a coolant – hot water vapor – in order to supplement the forces involved in the separation of minerals with surface forces of structural origin. In the accepted flotation mode, the influence of surface flows under the action of shear stresses – capillary-concentration, thermocapillary and thermoosmotic flows – on the kinetics of thinning and breakthrough of the interfacial film is proposed to be taken into account in the form of a correction to the slip length of the liquid in the hydrophobic gap. The correction value is expressed in fractions of the limiting thickness of the wetting film, which is determined from the condition of invariance of its thickness when the flows in the interfacial gap are equal – outflowing (due to the action of clamping force) and inflowing (Marangoni flows and thermoosmotic flow). On samples of gold-bearing ores from two deposits, experiments were carried out on gold flotation under conditions simulating a continuous process. The technological advantages of the developed scheme and regime of gold microdispersion flotation are shown in comparison with the basic technology.

Keywords: gold microdispersions, flotation, carrier minerals, wetting film, stability, slip, correction, flow kinetics, continuous process.
For citation:

Evdokimov S. I., Guseva E. A., Konstantinova M. V., Filushina E. V., Tynchenko Ya. A. Analysis of the kinetics of the flow of wetting films in flotation processes. MIAB. Mining Inf. Anal. Bull. 2023;(11-1):207-225. [In Russ]. DOI: 10.25018/0236_1493_2023_111_0_207.

Acknowledgements:

The study was supported by the Russian Science Foundation, Grant No. 23-27-00093.

Issue number: 11
Year: 2023
Page number: 207-225
ISBN: 0236-1493
UDK: 622.765
DOI: 10.25018/0236_1493_2023_111_0_207
Article receipt date: 10.07.2023
Date of review receipt: 15.09.2023
Date of the editorial board′s decision on the article′s publishing: 10.10.2023
About authors:

S.I. Evdokimov, Cand. Sci. (Eng.), Assistant Professor, North Caucasus Mining-and-Metallurgy Institute (State Technological University), 362021, Vladikavkaz, Republic of North Ossetia-Alania, Russia, e-mail: eva-ser@mail.ru,
E.A. Guseva1, Cand. Sci. (Eng.), Assistant Professor, e-mail: el.guseva@rambler.ru,
M.V. Konstantinova1, Cand. Sci. (Eng.), Assistant Professor, e-mail: mavikonst@mail.ru,
E.V. Filushina2,3, Cand. Sci. (Eng.), Assistant Professor, e-mail: ies_ief@mail.ru,
Ya.A. Tynchenko2,3, Graduate Student,
1 Irkutsk National Research Technical University, 664074, Irkutsk, Russia,
2 Reshetnev Siberian State University of Science and Technology, 660037, Krasnoyarsk, Russia,
3 Siberian Federal University, 660041, Krasnoyarsk, Russia.

 

For contacts:

S.I. Evdokimov, e-mail: eva-ser@mail.ru.

Bibliography:

1. Xing Y., Xu M., Gui X., Cao Y., Rudolph M., Butt Y.-J., Kappl M. The role of surface forces in mineral flotation. Current Opinion in Colloid & Interface Science. 2019, vol. 44, pp. 143—152. DOI: 10.1016/j.cocis.2019.11.005.

2. Gerasimenko T. E., Rubayeva I. O., Maksimov R. N., Vasiliev V. V. Peculiarities of poly disperse particle interaction in gold micro dispersions flotation processes. Sustainable Development of Mountain Territories. 2023, vol. 15, no. 1, pp. 97—113. DOI: 10.21177/1998-4502-2023-15-1-97-113.

3. Evdokimov S. I., Gerasimenko T. E., Maksimov R. N., Klykov Yu. G. Analysis of conjugate heat and mass transfer during aerosol flotation of gold from placers. Sustainable Development of Mountain Territories. 2022, vol. 14, no. 2, pp. 163—175. DOI: 10.21177/1998-4502-2022-14-2-163-175.

4. Gutarevich V. O., Klyuev R. V., Kukartsev V. A., Kukartsev V. V., Iushkova L. V., Korpacheva L. N. Reducing oscillations in suspension of mine monorail track. Applied Sciences. 2023, vol. 13, article 4671. DOI: 10.3390/app13084671.

5. Konyukhov V. Y., Permyakova D. N., Oparina T. A. Perspective for the use of industrial waste in lubricating compositions to reduce wear in friction pairs. Journal of Physics: Conference Series. 2021, vol. 2061, no. 1, article 012046. DOI: 10.1088/1742-6596/2061/1/012046.

6. Alizadeh M., Abdollahy M., Khalesi M. The effect of particle size analysis on bubble loading in column flotation using the models of sub-processes. Journal of Mining Engineering. 2017, vol. 12, no. 36, pp. 95—109.

7. Chen S., Zhou Y., Liu R., Zhou A., Qu J., Liu L., Zhang N., Yu Y., Zhu Z., Chang J., Tao X., Yuan X., Li Z. Comparison of attachment process of particles to air and oily bubbles in flotation. Advanced Powder Technology. 2023, vol. 34, no. 7, article 104059. DOI: 10.1016/j. fuel.2018.08.131.

8. Zawala J., Kosior D. Dynamics of dewetting and bubble attachment to rough hydrophobic surfaces — Measurements and modelling. Minerals Engineering. 2016, vol. 85, pp. 112—122. DOI: 10.1016/j.mineng.2015.11.003.

9. Kondrtiev V. V., Govorkov A. S., Kolosov A. D., Gorovoy V. O. The development of a test stand for developing technological operation «flotation and separation of MD2. The deposition of nanostructures MD1» produce nanostructures with desired properties. International Journal of Applied Engineering Research. 2017, vol. 12, no. 22, pp. 12373—12377.

10. Ejenstam L., Ovaskainen L., Rodriguez-Meizoso I., Wagberd L., Pan J., Swerin A., Claesson Per. M. The effect of superhydrophobic wetting state on corrosion protection — The AKD example. Journal of Colloid and Interface Science. 2013, vol. 412, pp. 56—64. DOI: 10.1016/j.jcis.2013.09.006.

11. Gozbenko V. E., Khomenko A. P., Kargapoltsev S. K., Minaev N. V. Creating of the alternative lubricants and practice of their use. International Journal of Applied Engineering Research. 2017, vol. 12, no. 22, pp. 12369—12372.

12. Feuillebois F., Bazant M. Z., Vinogradova O. I. Effective slip over superhydrophobic surfaces in thin channels. Physical Review Letters. 2009, vol. 102, article 026001. DOI: 10.1103/ PhysRevLett.102.026001.

13. Li C., Li D., Zhang H. Surface nanobubbles on the hydrophobic surface and their implication to flotation. International Journal of Minerals, Metallurgy and Materials. 2022, vol. 29, no. 8, pp. 1491—1492. DOI: 10.1007/s12613-021-2279-1.

14. Jadhav A., Barigou M. Bulk nanobubbles or not nanobubbles: that is the question. Langmuir. 2020, vol. 36, no. 7, pp. 1699—1708. DOI: 10.1021/acs.langmuir.9b03532.

15. Malkin A. Ya., Patlazhan S. A. Wall slip for complex liquids — Phenomenon and its causes. Advances in Colloid and Interface Science. 2018, vol. 257, pp. 42—57.

16. Isametova M. E., Kononenko R. V., Skeeba V. Y., Absadykov B. N. Thermal Pulse Processing of Blanks of Small-Sized Parts Made of Beryllium Bronze and 29 NK Alloy. Materials. 2022, vol. 15, no. 19, article 6682. DOI: 10.3390/ma15196682.

17. Kondrat’ev V.V., Govorkov A. S., Lavrent’eva M.V., Sysoev I. A., Description of the heat exchanger unit construction, created in IRNITU. International Journal of Applied Engineering Research. 2016, vol. 11, no. 19, pp. 9979—9983.

18. Balanovsky A. E., Shtayger M. G. Plasma-arc surface modification of metals in a liquid medium. IOP Conference Series: Materials Science and Engineering. 2018, vol. 411, no. 1, article 012013. DOI: 10.1088/1757-899X/411/1/012013.

19. Konyuhov V. Yu., Gladkih A. M., Galyautdinov I. I., Kiseleva T. Yu. Ecological architecture: The green roofs. IOP Conference Series: Earth and Environmental Science. 2019, vol. 350, no. 1, article 012035. DOI: 10.1088/1755-1315/350/1/012035.

20. Ershov V. A., Kondratiev V. V., Karlina A. I., Kolosov A. D., Sysoev, I.A. Selection of control system parameters for production of nanostructures concentrates. Journal of Physics: Conference Series. 2018, vol. 1118, no. 1, article 012014 DOI: 10.1088/1742-6596/1118/1/012014.

21. Nikolov A., Lee J., Wasan D. DLVO surface forces in liquid films and statistical mechanics of colloid oscillatory structural forces in dispersion stability. Advances in Colloid and Interface Science. 2023, vol. 313, article 102847. DOI: 10.1016/j.cis.2023.102847.

22. Strateichuk D. M., Klyuev R. V., Gladkikh V. A., Kukartsev V. V., Tynchenko Y. A. Morphological features of polycrystalline cds1−xsex films obtained by screen-printing method. Crystals. 2023, vol. 13, no. 5, article 825. DOI: 10.3390/cryst13050825.

23. Adigamov R. R., Baraboshkin K. A., Mishnev P. A. Development of rolling procedures for pipes of K55 strength class at the laboratorial mill. CIS Iron and Steel Review. 2022, vol. 24. pp. 60—66. DOI: 10.17580/cisisr.2022.02.09.

24. Smith A. M., Borkovec M., Trefalt G. Forces between solid surfaces in aqueous electrolyte solutions. Advances in Colloid and Interface Science. 2020, vol. 275, article 102078. DOI: 10.1016/j.cis.2019.102078.

25. Kondratiev V. V., Nebogin S. A., Sysoev I. A., Gorovoy V. O. Description of the test stand for developing of technological operation of nano-dispersed dust preliminary coagulation. International Journal of Applied Engineering Research. 2017, vol. 12, no. 22, pp. 12809—12813.

26. Liu S., Xie L., Liu G., Zhong H., Zong H. Understanding the hetero-aggregation mechanism among sulfide and oxide minerals particles driven by bifunctional surfactants: Intensification flotation of oxide minerals. Minerals Engineering. 2021, vol. 169, article 106928. DOI: 10.1016/j.mineng.2021.106928.

27. Pan L., Yoon R.-H. Measurement of hydrophobic forces in thin liquid films of water between bubbles and xanthate-treated gold surfaces. Minerals Engineering. 2016, vol. 98, pp. 240—250. DOI: 10.1016/j.mineng.2016.09.005.

28. Matveeva T. N. Flotation reagents for finely disseminated gold extraction from unenriched ores and technogenic products. Sustainable Development of Mountain Territories. 2021, vol. 13, no. 2, pp. 201—207. [In Russ]. DOI: 10.21177/1998-4502-2021-13-2-201-207.

29. Pan L., Jung S., Yoon R.-H. A fundamental study on the role of collector in the kinetics of bubble-particle interaction. International Journal of Mineral Processing. 2012, vol. 106-109, pp. 37—41.

30. Wang J., Yoon R.-H., Morris J. AFM surface force measurements conducted between gold surface treated in xanthate solutions. International Journal of Mineral Processing. 2013, vol. 122, pp. 13—21. DOI: 10.1016/j.minpro.2013.03.005.

31. Kemppinen J., Aaltonen A., Sihvonen T., Leppinen J., Siren H. Xanthate degradation occurring in flotation process waters of a gold concentrator plant. Minerals Engineering. 2015, vol. 80. DOI: 10.1016/j.mineng.2015.05.014.

32. Sanakulov K. S., Vorobyov A. E., Kozyrev E. N., Lianzi Zh. Physical and chemical properties of gold nanoparticles in ores and catalysts. Sustainable Development of Mountain Territories. 2022, vol. 14, no. 4, pp. 676—684. [In Russ]. DOI: 10.21177/1998-4502-2022-14-4-676-684.

33. Efremenkov E. A., Shanin S. A., Martyushev N. V. Development of an algorithm for computing the force and stress parameters of a cycloid reducer. Mathematics. 2023, vol. 11, article 993. DOI: 10.3390/math11040993.

34. Martyushev N. V., Petrenko Y. N. Effects of crystallization conditions on lead tin bronze properties. Advanced Materials Research. 2014, vol. 880, pp. 174—178. DOI: 10.4028/www. scientific.net/AMR.880.174.

35. Ivashutenko A., Martyushev N., Vidayev I., Kostikov K. Influence of technological factors on structure and properties of alumina-zirconia ceramics. Advanced Materials Research. 2014, vol. 1040, pp. 845—849. DOI: 10.4028/www.scientific.net/AMR.1040.845.

36. Sysoev I. A., Ershov V. A., Kondrat’ev V.V. Method of controlling the energy balance of electrolytic cells for aluminum production. Metallurgist. 2015, vol. 59, no. 5-6, pp. 518—525. DOI: 10.1007/s11015-015-0134-1.

37. Ilyushin P., Kulikov A., Suslov K., Filippov, S. Consideration of distinguishing design features of gas-turbine and gas-reciprocating units in design of emergency control systems. Machines. 2021, vol. 9, no. 3, article 47. DOI: 10.3390/machines9030047.

38. Suslov K. V., Solonina N. N., Smirnov A. S. Smart meters for distributed filtering of high harmonics in Smart Grid. Energy and Electrical Drives. International Conference on Power Engineering. 2011, article 6036552. DOI: 10.1109/PowerEng.2011.6036552.

39. Feuillebois F., Bazant M. Z., Vinogradova O. I. Effective slip over superhydrophobic surfaces in thin channels. Physical Review Letters. 2009, vol. 102, article 026001. DOI: 10.1103/ PhysRevLett.102.026001.

40. Huang W., Huang J., Guo Z., Liu W. Icehobic/anti-icing properties of superhydrophobic surfaces. Advances in Colloid and Interface Science. 2022, vol. 304, article 102658. DOI: 10.1016/j.cis.2022.102658.

41. Evdokimov S. I., Gerasimenko T. E. Development of a flotation regime for gold ores using a mixture of air and water steam. Fiziko-tekhnicheskie problemy razrabotki poleznykh iskopaemykh. 2021, no. 2, pp. 162—177. [In Russ]. DOI: 10.15372/FTPRPI20210217.

42. Kondrakhin V. P., Klyuev R. V., Sorokova S. N., Efremenkov E. A., Valuev D. V., Mengxu Q. Mathematical modeling and multi-criteria optimization of design parameters for the gyratory crusher. Mathematics. 2023, vol. 11, no. 10, article 2345. DOI: 10.3390/math11102345.

43. Evdokimov S. I., Pan'shin A. M., Solodenko A. A. Mineralurgiya. T. 2. Uspekhi flotatsii [Mineralurgy. Vol. 2. Advances in flotation], Vladikavkaz, 2010, 992 p.

Подписка на рассылку

Подпишитесь на рассылку, чтобы получать важную информацию для авторов и рецензентов.