Effect of composition of metal-containing modifiers on flotation of sulfide minerals of nonferrous heavy metals: Analysis and modeling

The article presents the studies into the influence exerted by metal-containing modifiers on flotation of copper, zinc and pyrite sulfides contained in copper–zinc sulfide ore from a Ural’s deposit, and the results of modeling copper, iron and zinc recovery in concentrate of flotation II (rougher copper–zinc flotation) as function of percentage of each sulfate in their mixture. The study uses a fourth-order simplex algorithm for mixing the test modifiers at different percentage. The modifiers, namely, cupric sulfate (CuSO4), ferric sulfate (FeSO4) and zinc sulfate (ZnSO4), are mixed and entered in flotation II, which is the rougher copper–zinc flotation, as a matter of fact. The experimental data analysis shows that a mixture of iron sulfate (FeSO4) 25 g/t and cupric sulfate (CuSO4) 75 g/t, added in flotation II at the total mixture consumption of 100 g/t, allows reaching the maximal overall copper and zinc recovery of 137.6%. From the experimental flotation results, the relations between the recoveries of copper, zinc and pyrite in flotation concentrate and the percentages of each modifier at their total consumption of 100 g/t are obtained. The relations can be used in a system of dozing the listed reagents in copper–zinc flotation. The models were used to calculate the copper, iron and zinc recoveries in concentrate of flotation II. This enabled determining the mixture compositions which could lead to the maximal copper and zinc recoveries at the minimal iron recovery. According to the modeling results, it seems the most interesting to investigate the effect of the mixture of cupric and iron sulfates entered in flotation II.

Keywords: copper–zinc sulfide ore, Scheffe’s simplex lattice design method, modifier, reagent, flotation, recovery, copper, zinc, iron.
For citation:

Phyoe Kyaw Kyaw, Kyaw Zaya Ya, Goryachev B.E. Effect of composition of metal-containing modifiers on flotation of sulfide minerals of nonferrous heavy metals: Analysis and modeling. MIAB. Mining Inf. Anal. Bull. 2024;(7):142-154. [In Russ]. DOI: 10.25018/ 0236_1493_2024_7_0_142.

Acknowledgements:
Issue number: 7
Year: 2024
Page number: 142-154
ISBN: 0236-1493
UDK: 622.765
DOI: 10.25018/0236_1493_2024_7_0_142
Article receipt date: 19.12.2023
Date of review receipt: 19.02.2024
Date of the editorial board′s decision on the article′s publishing: 10.06.2024
About authors:

Phyoe Kyaw Kyaw1, Graduate Student, e-mail: bophyo1831993@gmail.com, ORCID ID: 0000-0003-3084-6771,
Kyaw Zaya Ya1, Ph.D. Internship-Department of Mineral Processing, e-mail: kokyawgyi49@gmail.com, ORCID ID: 0000-0003-4364-9574,
B.E. Goryachev1, Dr. Sci. (Eng.), Professor, e-mail: beg@misis.ru,
1 NUST MISIS, 119049, Moscow, Russia.

 

For contacts:

Phyoe Kyaw Kyaw, B.E. Goryachev, e-mail: bophyo1831993@gmail.com; e-mail: beg@misis.ru.

Bibliography:

1. Bocharov V. A., Ignatkina V. A. Technology of mineral enrichment. T. 2: Mineral'no-syr'evaya baza poleznykh iskopaemykh. Obogashchenie rud tsvetnykh metallov, rud i rossypey redkikh metallov [Vol. 2.: Mineral resource base of minerals. Enrichment of ores of non–ferrous metals, ores and placers of rare metals], Moscow, Ruda i metally. 2007, pp. 156—170.

2. Abramov A. A., Leonov S. B. Obogashchenie rud tsvetnykh metallov [Enrichment of non-ferrous metal ores], Moscow, Nedra, 1991, 407 p.

3. Bocharov V. А., Ignatkina V. A., Abrytin D. V., Kayumov А. А., Kayumova V. R. (Korzh). Effect of sulfoxide-based modifiers on sulfide mineral floatability and on production data of ore flotation. MIAB. Mining Inf. Anal. Bull. 2022, no. 12, pp. 20—33. [In Russ]. DOI: 10.25018/0236_1493_2022_12_0_20.

4. Štirbanović Z. The effect of degree of liberation on copper recovery from copper-pyrite ore by flotation. Separation Science and Technology. 2020, vol. 55, no. 17, pp. 3260—3273. DOI: 10.1080/ 01496395.2019.1676260.

5. Bocharov V. A., Ryskin M. Ya., Pospelov N. D. Development of technology for processing copper-zinc ores of the Urals. Tsvetnye Metally. 1979, no. 10-е, pp. 105—107. [In Russ].

6. Mitrofanov S. I. Enrichment of copper-zinc-pyrite ores of the Urals. Tsvetnye Metally. 1977, no. 1, pp. 53—56. [In Russ].

7. Abramov A. A. Flotatsionnye metody obogashcheniya [Flotation methods of enrichment], Moscow, Nedra, 1993, 412 p.

8. Goryachev B. E., Naing L. O., Nikolaev A. A. Features of pyrite flotation in one of the copperzinc deposits of the Ural region with potassium butyl xanthate and sodium dithiophosphate. Tsvetnye Metally. 2014, no. 6, pp. 16—22. [In Russ].

9. Yagudina Yu. R., Karasov Yu. K. Improving the technology of flotation of copper-zinc ores processed at the processing plant of the Aktobe copper company. Russian Mining Industry. 2021, no. S5-2, pp. 29—32. [In Russ].

10. Chanturiya V. A., Shadrunova I. V. Tekhnologiya obogashcheniya mednykh i medno-tsinkovykh rud Urala [Technology of enrichment of copper and copper-zinc ores of the Urals], Moscow, Nauka, 2016, 386 p.

11. Htet Zaw Oo, Kyaw Zay Ya, Goryachev B. E. Effect of iron/zinc vitriol–sodium sulphide blends on copper–zinc sulphide ore flotation. MIAB. Mining Inf. Anal. Bull. 2023, no. 12, pp. 139—

151. [In Russ]. DOI: 10.25018/0236_1493_2023_12_0_139.

12. Kuznetsov V. V., Aleksandrova T. N. Development of methods for determining the flotability of minerals for the effective design of flotation technology. MIAB. Mining Inf. Anal. Bull. 2022, no. 10-1, pp. 145—154. [In Russ]. DOI: 10.25018/0236_1493_2022_101_0_145.

13. Soroka E. I., Pritchin M. E., Lyutoev V. P., Smoleva I. V. Physico-chemical studies of carbonates of the Safyanovsky copper-pyrite deposit (Middle Urals). Bulletin of Perm university. Geology. 2019, no. 2, pp. 152—164. [In Russ].

14. Нnaing Lin Oo Povyshenie selektivnosti flotatsii kolchedannykh medno-tsinkovykh rud s ispol'zovaniem modifikatorov flotatsii pirita na osnove soedineniy zheleza (II) [Increasing the selectivity of flotation of pyrite copper-zinc ores using pyrite flotation modifiers based on iron (II) compounds], Candidate’s thesis, Moscow, MISiS, 2015, pp. 27. https://misis.ru/files/3192/Naing_avtoreferat.doc.

15. Kyaw Za Ya Povyshenie selektivnosti flotatsii kolchedannykh medno-tsinkovykh rud s ispol'zovaniem modifikatorov flotatsii sfalerita na osnove soedineniy zheleza (II), medi (II) i tsinka [Increasing the selectivity of flotation of pyrite copper-zinc ores using sphalerite flotation modifiers based on iron (II), copper (II) and zinc compounds], Candidate’s thesis, Moscow, MISiS, 2018, pp. 26. https:// misis.ru/files/9461/Chgo_AR.pdf.

16. Phyoe Kyaw Kyaw, Kyaw Zaya Ya, Goryachev B. E. Effect of composition of metal-bearing surface modifiers for sulfide minerals of base heavy metals in copper–zinc ore flotation. MIAB. Mining Inf. Anal. Bull. 2023, no. 11, pp. 128—142. [In Russ]. DOI: 10.25018/0236_1493_2023_11_0_128.

17. Scheffe H. Experiments with mixtures. Journal of the Royal Statistical Society: Series B (Methodological). 1958, vol. 20, no. 2, pp. 344—360. DOI: 10.1111/j.2517-6161.1958.tb00299.x.

18. Novik F. S. Planirovanie eksperimenta na simplekse pri izuchenii metallicheskikh sistem [Planning an experiment on a simplex in the study of metal systems], Moscow, Metallurgiya, 1985, 256 p.

19. Shumenko V. N. Methods of experiment planning. Experimental planning in the study of composition-properties diagrams. Planirovanie promyshlennykh eksperimentov [Planning of industrial experiments], Moscow, MISiS, 1979, 52 p.

20. Valery V., Hanna P., Yevhenia, Konstantin G. A modified scheffe's simplex lattice design method in development of ceramic carriers for catalytic neutralizers of gas emissions. Chemistry Journal of Moldova. 2021, vol. 16, pp. 79—87. DOI: 10.19261/cjm.2021.779.

21. Zedginidze I. G. Planirovanie eksperimenta dlya issledovaniya mnogokomponentnykh sistem [Experiment planning for the study of multicomponent systems], Moscow, Nauka, 1976, 390 p.

Our partners

Подписка на рассылку

Раз в месяц Вы будете получать информацию о новом номере журнала, новых книгах издательства, а также о конференциях, форумах и других профессиональных мероприятиях.