Bibliography: 1. Alborov I. D., Burdzieva O. G., Tedeeva F. G., Gegelashvili M. V. Ecological stress in nonferrous metal mining regions in the North Caucasus. MIAB. Mining Inf. Anal. Bull. 2020, no. 11-1, pp. 18—31. [In Russ]. DOI: 10.25018/0236-1493-2020-111-0-18-31.
2. Mihaljevič M., Baieta R., Ettler V., Vaněk A., Kříbek B., Penížek V., Drahota P., Trubač J., Sracek O., Chrastný V., Mapani B. S. Tracing the metal dynamics in semi-arid soils near mine tailings using stable Cu and Pb isotopes. Chemical Geology. 2019, vol. 515, pp. 61—76. DOI: 10.1016/j.chemgeo.2019.03.026.
3. Dulya O. V., Bergman I. E., Kukarskih V. V., Vorobeichik E. L., Smirnov G. Y., Mikryukov V. S. Pollution-induced slowdown of coarse woody debris decomposition differs between two coniferous tree species. Forest Ecology and Management. 2019, vol. 448, pp. 312—320. DOI: 10.1016/j.foreco.2019.06.026.
4. Antoninova N. Yu., Sobenin A. V., Shubina L. A. Assessment of usability of industrial waste in construction of geochemical barriers. MIAB. Mining Inf. Anal. Bull. 2020, no. 12, pp. 78—88. [In Russ]. DOI: 10.25018/0236-1493-2020-12-0-78-88.
5. Salpagarova S. I., Salpagarova Z. I. The Environmental Impacts of Urupsky Mining Complex. Dagestan state pedagogical university journal. Natural and exact sciences. 2018, vol. 12, no. 1, pp. 88—93. [In Russ].
6. Kabata-Pendias A., Pendias H. Trace elements in soils and plants. CRC. Taylor & Francis Group, Boca Raton, 2011.
7. D'yachenko V. V., Matasova I. Y. Regional clarkes of chemical elements in soils of southern European Russia. Eurasian Soil Science. 2016, no. 10, pp. 1159—1166. [In Russ]. DOI: 10.1134/ S1064229316100069.
8. Antoniadis V., Shaheen S., Levizou E., Shahid M., Niazi N., Vithanage M., Ok Y., Bolan N., Rinklebe J. A critical prospective analysis of the potential toxicity of trace element regulation limits in soils worldwide: are they protective concerning health risk assessment? A review. Environment International. 2019, vol. 127, pp. 819—847. DOI: 10.1016/j.envint.2019.03.039.
9. Neaman A., Yáñez K. Phytoremediation of soils contaminated by copper smelting in Chile: Results of a decade of research. Eurasian Soil Science. 2021, no. 12. C. 1564—1572. [In Russ]. DOI: 10.1134/S1064229321120085.
10. Kolesnikov S., Timoshenko А., Minnikova T., Tsepina N., Kazeev K., Akimenko Y., Zhadobin A., Shuvaeva V., Rajput V. D., Mandzhieva S., Sushkova S., Minkina T., Dudnikova T., Mazarji M., Alamri S., Siddiqui M. H., Kumar Singh R. Impact of metal-based nanoparticles on cambisols microbial functionality, enzyme activity and plant growth. Plants. 2021, vol. 10, no. 10, article 2080. DOI: 10.3390/plants10102080.
11. Yakovlev A. S., Evdokimova M. V. Approaches to the regulation of soil pollution in russia and foreign countries. Eurasian Soil Science. 2022, no. 5, pp. 631—641. [In Russ]. DOI: 10.31857/S0032180X22050136.
12. Araújo E., Strawn D. G., Morra M., Moore A., Ferracciú Alleoni L. R. Association between extracted copper and dissolved organic matter in dairy-manure amended soils. Environmental Pollution. 2019, vol. 246, pp. 1020—1026. DOI: 10.1016/j.envpol.2018.12.070.
13. Ju W., Liu L., Fang L., Cui Y., Duan C., Wu H. Impact of co-inoculation with plantgrowth-promoting rhizobacteria and rhizobium on the biochemical responses of alfalfa-soil system in copper contaminated soil. Ecotoxicology and Environmental Safety. 2019, vol. 167, pp. 218—226. DOI: 10.1016/j.ecoenv.2018.10.016.
14. Kolesnikov S. I., Kazeev K. Sh., Timoshenko A. N., Akimenko Yu. V., Myasnikova M. A. Ecotoxicity of copper, nickel, and zinc nanoparticles assessment on the basis of biological indicators of chernozems. Eurasian Soil Science. 2019, no. 8, pp. 986—992. [In Russ]. DOI: 10.1134/ S106422931908009X.
15. Kolesnikov S. I., Kazeev K. Sh., Akimenko Yu. V. Development of regional standards for pollutants in the soil using biological parameters. Environmental Monitoring And Assessment. 2019, vol. 191, no. 9, pp. 544. DOI: 10.1007/s10661-019-7718-3.
16. Kolesnikov S., Minnikova T., Kazeev K., Akimenko Y., Evstegneeva N. Assessment of the ecotoxicity of pollution by potentially toxic elements by biological indicators of haplic chernozem of Southern Russia (Rostov region). Water, Air, and Soil Pollution. 2022, vol. 233, no. 1, pp. 18. DOI: 10.1007/s11270-021-05496-3.
17. Nazir F., Hussain A., Fariduddin Q. Hydrogen peroxide modulate photosynthesis and antioxidant systems in tomato (Solanum lycopersicum L.) plants under copper stress. Chemosphere. 2019, vol. 230, pp. 544—558. DOI: 10.1016/j.chemosphere.2019.05.001.
18. Zeng Q., Ling Q., Wu J., Yang Z., Liu R., Qi Y. Excess copper-induced changes in antioxidative enzyme activity, mineral nutrient uptake and translocation in sugarcane seedlings. Bulletin of Environmental Contamination and Toxicology. 2019, vol. 103, no. 6, pp. 834—840. DOI: 10.1007/s00128-019-02735-6.
19. Shabbir Z., Sardar A., Shabbir A., Abbas G., Shamshad S., Khalid S., Ghulam Murtaza N., Dumat C., Shahid M. Copper uptake, essentiality, toxicity, detoxification, and risk assessment in soil-plant environment. Chemosphere. 2020, vol. 259, article 127436. DOI: 10.1016/j.chemosphere.2020.127436.
20. Saleem M. H., Kamran M., Zhou Y., Parveen A., Rehman M., Ahmar S., Liu L. Appraising growth, oxidative stress and copper phytoextraction potential of flax (Linum usitatissimum L.) grown in soil differentially spiked with copper. Journal of Environmental Management. 2020, vol. 257, article 109994. DOI: 10.1016/j.jenvman.2019.109994.
21. Guo Z., Megharaj M., Beer M., Ming H., Rahman M. M., Wu W., Naidu R. Heavy metal impact on bacterial biomass based on DNA analyses and uptake by wild plants in the abandoned copper mine soils. Bioresource Technology. 2009, vol. 100, no. 17, pp. 3831—3836. DOI: 10.1016/j.biortech.2009.02.043.
22. Fokina A. I., Ashikhmina T. Ya., Domracheva L. I., Gornostaeva E. A., Ogorodnikova S. Yu. Heavy Metals as a Factor of Microorganisms Metabolism Changes (Review). Theoretical and applied ecology. 2015, no. 2, pp. 5—17. [In Russ].
23. Fernández-Calviño D., Nóvoa-Muñoz J. C., López-Periago E., Arias-Estévez M. Changes in copper content and distribution in young, old and abandoned vineyardacid soils due to land use changes. Land Degradation and Development. 2008, vol. 19, pp. 165—177. DOI: 10.1111/ j.1398-9995.2007.01620.
24. Shein E. V. Granulometric composition of soils: methods of laser difraction and sedimentometry, their comparison and use. Eurasian Soil Science. 2009, no. 3, pp. 309—317. [In Russ].
25. Minkina T. M., Motuzova G. V., Mandzhieva S. S., Nazarenko O. G. Ecological resistance of the soil-plant system to contamination by heavy metals. Journal of Geochemical Exploration. 2012, vol. 123, pp. 33—40.
26. Dobrovol'skiy G. V., Nikitin E. D. Funktsii pochv v biosfere i ekosistemakh (ekologicheskoe znachenie pochv) [Functions of soils in the biosphere and ecosystems (ecological significance of soils)], Moscow, Nauka, 1990, 261 p.