Characteristics of magnetic beneficiation of Waelz clinker from electric arc furnace dust processing using various field density

The present study addresses the challenge of the utilization of Waelz clinker, which is formed during the treatment of electric arc furnace dust, for the recovery of iron and associated non-ferrous metals. The investigation focused on Waelz clinker samples from two Russian metallurgical plants – PJSC «CZP» and LLC «Alfatrans». The aim of the research was to assess the efficiency of magnetic separation under varying magnetic field density and to identify optimal conditions for the selective recovery of valuable elements. Wet magnetic beneficiation was conducted within a magnetic density range of 0.05–1.6 T followed by quantitative chemical analysis of the separated products. The results demonstrated that high-gradient magnetic separation is ineffective for iron recovery due to the ultrafine dissemination of iron-bearing phases. Sequential four-stage separation results revealed distinctions in the distribution of iron, copper, and zinc between magnetic and non-magnetic fractions for different clinker samples, which can be attributed to variations in mineralogical composition and particle size distribution of iron phases. The optimal separation conditions were identified as 0.1 T for the clinker from PJSC «CZP» and 0.2 T for that from LLC «Alfatrans». The magnetic concentrate obtained from the PJSC «CZP» sample can be utilized as a copper-bearing intermediate product for copper metallurgy or as a feed for the production of corrosion-resistant steel grades.

Keywords: magnetic separation, magnetic beneficiation, Waelz clinker, electric arc furnace dust, recovery, iron, zinc, copper, Waelz process.
For citation:

Grudinsky P. I., Anisonyan K. G., Dyubanov V. G. Characteristics of magnetic beneficiation of Waelz clinker from electric arc furnace dust processing using various field density. MIAB. Mining Inf. Anal. Bull. 2025;(9-1):41-54. [In Russ]. DOI: 10.25018/0236_ 1493_2025_91_0_41.

Acknowledgements:

This research was funded by the Russian Science Foundation, Grant No. 24-23-00507, https://rscf.ru/project/24-23-00507/.

Issue number: 9-1
Year: 2025
Page number: 41-54
ISBN: 0236-1493
UDK: 658.567.1
DOI: 10.25018/0236_1493_2025_91_0_41
Article receipt date: 03.06.2025
Date of review receipt: 27.07.2025
Date of the editorial board′s decision on the article′s publishing: 10.08.2025
About authors:

P.I. Grudinsky1, Junior Researcher, e-mail: pgrudinskiy@imet.ac.ru, ORCID ID: 0000-0002-7358-150X,
K.G. Anisonyan1, Senior Researcher, e-mail: kanisonyan@imet.ac.ru, ORCID ID: 0009-0001-7208-662Х,
V.G. Dyubanov1, Cand. Sci. (Eng.), Leading Researcher, e-mail: vdyubanov@imet.ac.ru, ORCID ID: 0009-0001-5830-7799,
1 Institution of Russian Academy of Sciences A.A. Baikov Institute of Metallurgy and Material Science RAS (A.A. Baikov IMET RAS), Moscow, 119334, Russia.

 

For contacts:

P.I. Grudinsky, e-mail: pgrudinskiy@imet.ac.ru.

Bibliography:

1. Zhang Z. X., Hou D. F., Aladejare A., Ozoji T., Qiao Y. World mineral loss and possibility to increase ore recovery ratio in mining production. International Journal of Mining, Reclamation and Environment. 2021, vol. 35, no. 9, pp. 670—691. DOI: 10.1080/17480930.2021.1949878.

2. Beylot A., Dewulf J., Greffe T., Muller S., Blengini G. A. Mineral resources depletion, dissipation and accessibility in LCA: a critical analysis. International Journal of Life Cycle Assessment. 2024, vol. 29, no. 5, pp. 890—908. DOI: 10.1007/s11367-023-02278-3.

3. Golik V. I., Titova A. V. Prospects for increasing the mineral base of the non-ferrous metallurgy. Russian Mining Industry Journal. 2024, no. 3, pp. 77—84. [In Russ]. DOI: 10.30686/1609-9192-20243-77-84.

4. Golik V. I., Titova A. V., Titov G. I. On utilization of concentration tailings of non-ferrous metal ores. Russian Mining Industry Journal. 2023, no. 5, pp. 96—101. [In Russ]. DOI: 10.30686/1609-91922023-5-96-101.

5. Rusanov I. F., Kuberskiy S. V., Protsenko M. Yu., Zavgorodniy S. R. Recycling of solid industrial waste in ferrous metallurgy. Ecological Bulletin of Donbass. 2022, no. 4, pp. 41—48. [In Russ].

6. Makhathini T. P., Bwapwa J. K., Mtsweni S. Various options for mining and metallurgical waste in the circular economy: A review. Sustainability. 2023, vol. 15, no. 3, article 2518. DOI: 10.3390/ su15032518.

7. Whitworth A. J., Vaughan J., Southam G., Van Der Ent A., Nkrumah P. N., Ma X., Parbhakar-Fox A. Review on metal extraction technologies suitable for critical metal recovery from mining and processing wastes. Minerals Engineering. 2022, vol. 182, article 107537. DOI: 10.1016/j. mineng.2022.107537

8. Di Maria A., Merchán M., Marchand M., Eguizabal D., De Cortázar M. G., Van Acker K. Evaluating energy and resource efficiency for recovery of metallurgical residues using environmental and economic analysis. Journal of Cleaner Production. 2022, vol. 356, article 131790. DOI: 10.1016/j. jclepro.2022.131790.

9. Makarov A. B., Talalay A. G., Guman O. M., Khasanova G. G. Anthropogenic deposits and their impact on the natural environment. Gornyi Zhurnal. 2022, no. 3, pp. 120—129. DOI: 10.21440/05361028-2022-3-120-129.

10. Li Y., Feng H., Wang J., She X., Wang G., Zuo H., Xue Q. Current status of the technology for utilizing difficult-to-treat dust and sludge produced from the steel industry. Journal of Cleaner Production. 2022, vol. 367, article 132909. DOI: 10.1016/j.jclepro.2022.132909.

11. De Araújo Neto A. P., Sales F. A., Ramos W. B., Brito R. P. Thermo-environmental evaluation of a modified Waelz process for hazardous waste treatment. Process Safety and Environmental Protection. 2021, vol. 149, pp. 442—450. DOI: 10.1016/j.psep.2020.11.021.

12. Uppalwar C. S., Thakur A. N., Gujar J. G., Sonawane S. S. Recovery of zinc from a variety of industrial wastes. Metal Value Recovery from Industrial Waste Using Advanced Physicochemical Treatment Technologies. Amsterdam: Elsevier, 2025, pp. 335—363. DOI: 10.1016/B978-0-44321884-2.00009-5.

13. Panshin A. M., Leontyev L. I., Kozlov P. A., Dyubanov V. G., Zatonsky A. V., Ivakin D. A. Reprocessing technology of electric arc furnace dust Join Stock Company «Severstal» in Waelz treating of complex Join Stock Company «Chelyabinsk Zink Plant». Ecology and Industry of Russia. 2012, no. 11, pp. 4—6. [In Russ]. DOI: 10.18412/1816-0395-2012-11-4-6.

14. Drozdov M. I. Recycling of metallurgical waste using Waelz technology: environmental and economic impact on the Ural Federal District. Rossiyskie regiony v fokuse peremen: sbornik dokladov XVIII Mezhdunarodnoy konferentsii [Russian regions in the focus of change: collection of reports from the XVIII International Conference], Ekaterinburg, 2023, pp. 675—678. [In Russ].

15. Kozlov P. A., Panshin A. M., Yakornov S. A., Ivakin D. A. Development and implementation of technology for processing ferrous metallurgy dust — transition to a closed-loop economy for the implementation of waste-free technological processes. Trudy VI Kongressa c mezhdunarodnym uchastiem TEKhNOGEN-2023 [Proceedings of VI Congress with international participation TECHNOGEN-2023], Ekaterinburg, UroRAN, 2023, pp. 36—40. [In Russ]. DOI: 10.34923/technogen-ural. 2023.49.60.005.

16. Onuk P., Melcher F. Mineralogical and chemical quantification of waelz slag. International Journal of Mineral Processing and Extractive Metallurgy. 2022, vol. 7, no. 2, article 50. DOI: 10.11648/ j.ijmpem.20220702.13.

17. Ushakova M. V., Bizhanov A. M. On the efficiency of recycling secondary materials in ferrous metallurgy. Problems of ferrous metallurgy and materials science. 2025, no. 1, pp. 134—140. [In Russ]. DOI: 10.52351/00260827_2025_1_134.

18. Bae H. R., Barna R., Méhu J., Van Der Sloot H., Moszkowicz P., Desnoyers C. Assessment of chemical sensitivity of waelz slag. Studies in Environmental Science. 1997, vol. 71, pp. 647—660. DOI: 10.1016/S0166-1116(97)80248-8.

19. Mitrofanov P. A., Ovsyannikov A. O., Fedorov A. S., Bragin V. V., Vokhmyakova I. S., Nikitin A. D., Bersenev I. S. Patent RU 2819890. 2024. [In Russ].

20. Khanapur N. V., Tripathi B., Chandra T. Incorporating Waelz slag to strengthen the properties of fine recycled aggregate concrete. Journal of Building Engineering. 2025, vol. 104, article 112235. DOI: 10.1016/j.jobe.2025.112235.

21. Salas I., Cifrian E., Andres A., Viguri J. R. Self-organizing maps to assess the recycling of waste in ceramic construction materials. Applied Sciences. 2021, vol. 11, no. 21, article 10010. DOI: 10.3390/app112110010.

22. Zemnukhova L. A., Falaleeva N. A. Non-ferrous metallurgy slags: washing-out of heavy metals and perspectives of their usage in construction. Vestnik of the Far East Branch of the Russian Academy of Sciences. 2011, no. 5, pp. 115—118. [In Russ].

23. Liu Z., Ma H., Liu Z., Li Q. Novel process for comprehensive utilization of iron concentrate recovered from zinc kiln slag. Extraction 2018. Cham: Springer, 2018. pp. 1765—1776. DOI: 10.1007/978-3-319-95022-8_146.

24. Meng X., Li Y. Process optimization of preparing glass-ceramic from secondary slag of zinc extraction. Nonferrous Metals Science and Engineering. 2020, vol. 11, no. 2, pp. 27—33. [In Chinese]. DOI: 10.13264/j.cnki.ysjskx.2020.02.004

25. Pichler C., Antrekowitsch J. Recycling of zincand lead-bearing residues with pyrolysis gas. JOM. 2015, vol. 67, no. 9, pp. 2038—2046. DOI: 10.1007/s11837-015-1552-z.

26. Han Y., Kim S., Han S., Kim Y. The optimal physical treatment process for production of highgrade iron concentrate from waelz kiln slag. Resources Recycling. 2023, vol. 32, no. 2, pp. 3—11. [In Korean]. DOI: 10.7844/kirr.2023.32.2.3.

27. Grudinsky P., Yurtaeva A., Pankratov D., Pasechnik L., Musaelyan R., Dyubanov V. The waelz slag from electric arc furnace dust processing: characterization and magnetic separation studies. Materials. 2024, vol. 17, no. 10, article 2224. DOI: 10.3390/ma17102224.

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