Compound collectors based on oil products for frother separation of diamond-bearing kimberlites

Performance of frother separation of diamond-bearing ore can be enhanced through the use of effective collectors. The research findings show that such compound collectors for frother separation of diamonds can be produced from mixing of oil products and oil at certain ratios maintained between the main fractions of light distillates, petroleum oils, resins and asphaltenes. For the activity tests of compound collectors, bunker oil and activated water-in-oil emulsions WOE-U and WOE-10 from Udachny and Internatsionalny mines, respectively, were mixed at various ratios and were used in the tests as collecting agents. The highest diamond recovery in the frother separation concentrates is achieved when the mass fractions of light distillates is 35–48%, petroleum oils—32–40%, and resin and asphaltenes—17–24%. A nearly optimal fractional makeup of a compound collector and the higher diamond recovery is obtained in frother separation with a mix of diesel fuel, bunker oil and water-in-oil emulsions. The resultant diamond concentration after frother separation with the WOE–diesel fuel compound collector exceeds the diamond recovery with bunker oil F-5 by 1.1–1.5%. The test results allow recommending the compound collectors of the proposed fractional makeup for the efficient frother separation of fine diamonds from diamond-bearing kimberlites.

Keywords: frother separation, diamonds, compound collectors, water-in-oil emulsion, bunker oil, diesel fuel, fractions.
For citation:

Morozov V. V., Lezova S. P. Compound collectors based on oil products for frother separation of diamond-bearing kimberlites. MIAB. Mining Inf. Anal. Bull. 2020;(12):137-146. [In Russ]. DOI: 10.25018/0236-1493-2020-12-0-137-146.

Acknowledgements:
Issue number: 12
Year: 2020
Page number: 137-146
ISBN: 0236-1493
UDK: 622.765.4
DOI: 10.25018/0236-1493-2020-12-0-137-146
Article receipt date: 05.07.2020
Date of review receipt: 17.08.2020
Date of the editorial board′s decision on the article′s publishing: 10.11.2020
About authors:

V.V. Morozov1, Dr. Sci. (Eng.), Professor, e-mail: dchmggu@mail.ru,
S.P. Lezova1, Senior Lecturer, e-mail: svlezova@mail.ru,
1 National University of Science and Technology «MISiS», 119049, Moscow, Russia.

 

For contacts:

V.V. Morozov, e-mail: dchmggu@mail.ru.

Bibliography:

1. Chanturiya V.A. Innovation-based processes of integrated and high-level processing of natural and technogenic minerals in Russia. Innovative Technologies Are Key to Successful Mineral Processing. Book of Abstracts. Procedings of 29th International Mineral Processing Congress. Moscow, 2018. Pp. 2—4.

2. Chanturia V.A., Dvoichenkova G. P., Ostrovskaya G. H., Kovalenko E. G. Efficiency of application of the foam separation process at ALROSA factories due to activation of reagentscollectors. Gornyi Zhurnal. 2010, no 7, pp. 72—74. [In Russ].

3. Zlobin M. N. Technology of coarse-grained flotation in the enrichment of diamond-containing ores. Gornyi Zhurnal. 2011, no 1, pp. 87—89. [In Russ].

4. Verkhoturov M. V., Amelin S. A., Konnova N. I. Diamond enrichment. International Journal of Experimental Education. 2012, no 2, pp. 61. [In Russ].

5. Makhrachev A. F., Dvoychenkova G. P., Lezova S. P. Analysis and optimization of compositions of compound collectors for frother separation of diamonds. MIAB. Mining Inf. Anal. Bull. 2018, no 11, pp. 178—185. [In Russ]. DOI: 10.25018/0236-1493-2018-11-0-178-185.

6. Chanturia V.A., Dvoichenkova G. P., Ostrovskaya G. H., Makhrachev A. F., Kovalchuk O. E. Modification of properties and experimental approbation of water-oil emulsions as collecting reagents for the process of foam separation of diamond-containing raw materials. Rudy i metally. 2013, no 5, pp. 58—64. [In Russ].

7. Makhrachev A. F., Dvoichenkova G. P., Lezova S. P. Research and application of compound collectors for foam separation of diamond-containing kimberlites. Materialy mezhdunarodnogo soveshchaniya «Plaksinskie chteniya-2018» [Proceedings of International Meeting Plaksin’s Lectures-2018], Moscow, 2018, pp. 69—71. [In Russ].

8. Liu L., Cheng G., Yu W., Yang C. Flotation collector preparation and evaluation of oil shale. Oil Shale. 2018. Vol. 35. No. 3. Pp. 242–25.

9. Vakhonina T. E. Klein M. S. Prospects for the use of spent mineral oils for the production of flotation reagents. Sovremennye tendentsii i innovatsii v nauke i proizvodstve. Materialy IV mezhdunarodnoy nauchno-prakticheskoy konferentsii [Modern trends and innovations in science and production Materials of the IV international scientific and practical conference], Kemerovo, 2015, pp. 112—113. [In Russ].

10. Stepanova M. N. Organicheskie reagenty vo flotatsii: uchebnoe posobie [Organic reagents in flotation, Educational aid], Perm, Izd-vo PGTU, 2009, 53 p.

11. Speight J. G. The chemistry and technology of petroleum. 2014, CRC Press. 953 p.

12. Nefteprodukty. Terminy i opredeleniya. GOST 26098-84. [Petroleum products. Terms and definitions. State standard 26098-84], Moscow, Standardinform, 2010, 96 p.

13. Kuzina Z. P., Min R. S., Samoylov V. G. Sulfur-aromatic oil concentrates-effective apolar reagents. Tezisy doklada 2-go kongressa obogatiteley stran SNG [Theses of report of the 2nd Congress of CIS concentrators], Moscow, Al'teks, 1999, pp. 62. [In Russ].

14. Treese S. A., Pujado P. R., Jones D. S. J. Handbook of petroleum processing. 2nd edition, Springer, 2015, 1913 p.

15. Morozov V. V. Pestryak I. V., Erdenezul Zh. Influence of the concentration of a non-ionic collector — allyl ether of amylxanthogenic acid on the flotation of copper-molybdenum ores. Tsvetnye metally. 2018, no 11, pp. 14—20. [In Russ].

16. Petukhov V. N., Skorobogatova A. A., Ilyasova A. Z. Research of flotation activity of reagents-collectors of various group chemical composition during coal flotation. Teoriya i tekhnologiya metallurgicheskogo proizvodstva. 2017, no 1, pp. 16—19. [In Russ].

17. Zhanga J., Kouznetsov D. L., Yu M., Rylatt M., Yoon R. H. Improving the separation of diamond from gangue minerals. Minerals Engineering. 2012. Vol. 36–38. Pp. 168—171.

18. Kasomo R. M., Ombiro S., Rop B., Mutua N. M. Investigation and comparison of emulsified diesel oil and flomin C 9202 as a collector in the beneficiation of ultra-fine coal by aggloflotation. International Journal of Oil, Gas and Coal Engineering. 2018. Vol. 6. No 4. Pр. 74—80.

19. Morozov V. V., Lezova S. P. Optimization of the composition of compound collectors for foam separation of diamond-containing kimberlites. Tezisy XXV Mezhdunarodnoy nauchnotekhnicheskoy konferentsii «Nauchnye osnovy i praktika pererabotki rud i tekhnogennogo syr'ya» [Theses of the XXV International scientific and technical conference «Scientific bases and practice of processing of ores and technogenic raw materials»], Ekaterinburg, 2020, pp. 33—36. [In Russ].

Our partners

Подписка на рассылку

Раз в месяц Вы будете получать информацию о новом номере журнала, новых книгах издательства, а также о конференциях, форумах и других профессиональных мероприятиях.